The face in the shade
The idea of the whole picture is here. Leave the upper face in the shadow of the brim, but keep the shadow transparent and warm, lit by daylight reflected up from below, so that the eyes read clearly; then bring the full sun onto the chin, the throat and the chest.
In this second version, the infrared image shows, you first painted the mouth more closed, with less of the teeth showing, and the eyelids lower over the whites of the eyes. That is close to how the face looks in the panel.
